Data Set Synoptic Stream Surveys: pH & Chemistry
PEARL ID GMC15
PEARL Category Water Quality
Data Provider Senator George J. Mitchell Center for Environmental & Watershed Research
Provider Contact Name Ken Johnson
  Affiliation GMC
  E-mail ken.johnson@umit.maine.edu
  Web-site www.umaine.edu/waterresearch
Data Status (Ongoing / Complete) Ongoing
First Upload to PEARL June 7, 2005
Latest Upload to PEARL September 30, 2005
Metadata Revised September 30, 2005
First Year in Data Set 2003
Most Recent Year in Data Set 2004
Number of Years with Data 2
Waterbody Type(s) Streams
Number of Sites Sampled Approximately 70 sites in 13 drainages, including all 8 drainages with endangered populations of Atlantic salmon.
Abstract

Salmon are potentially susceptible to changes in water quality caused by both natural fluctuations in chemical concentrations and climate variability, as well as anthropogenic introduction of pollutants and changes in land-use patterns.  Non-point-source pollution, including any resulting from agriculture and commercial logging operations, can affect water chemistry in the rivers. 

A 2002 report to the Maine Atlantic Salmon Technical Advisory Committee titled “Water Quality Issues as Potential Limiting Factors Affecting Juvenile Atlantic Salmon Life Stages in Maine Rivers” postulated that acidification from acid rain could be adversely affecting the survival of Atlantic salmon in some Maine rivers.  This report was prepared by an Ad Hoc Committee on Water Quality, made up of scientists from the Atlantic Salmon Commission, Department of Environmental Protection (DEP), University of Maine, Penobscot Indian Nation (PIN), U.S. Fish and Wildlife Service (USFWS), United States Geological Survey (USGS), and Maine Department of Inland Fisheries and Wildlife (MDIFW).

In 2003, the Atlantic Salmon Commission began collaborative efforts with the Senator George Mitchell Center for Environmental and Watershed Research at the University of Maine (GMC) to investigate baseline and precipitation event driven chemical conditions that exist in Maine salmon rivers during different hydrologic conditions.  The Mitchell Center has been involved for over 15 years in watershed research, developing new methods and operating under EPA QA/QC guidelines and reporting requirements.  The Center has been the laboratory for EPA Long Term Monitoring in Maine since 1983.

The first objective of the pH survey was to create three seasonal snapshots of pH related water chemistry in Maine salmon rivers.  This sample scheme allowed for comparisons both within and among watersheds under similar flow and precipitation conditions.  Water samples were collected on the same day in spring, summer, and fall from 74 sites across 13 Downeast and central Maine river systems, including all eight drainages with Endangered population of Atlantic salmon.  Samples were analyzed at the Mitchell Center for closed-cell pH, air-equilibrated pH, acid neutralizing (buffering) capacity (ANC), apparent color, and conductivity.  A cation/anion series was also analyzed for. The spring and fall sample days each coincided with peak flow conditions following significant rain events.  The summer sample occurred at normal low flow conditions.

The project was funded by the Atlantic Salmon Commission.

 
Key References Johson, K. and J.S. Kahl.  2005.  A systematic survey of water chemistry for Downeast area rivers.  Project final report to Maine Atlantic Salmon Commission.
Map Click HERE to view map of sites sampled for this data set.
Data Fields:  Field Name Unit Description
Water Code Stream segment code from the USGS National Hydrographic Database.
Waterbody Name Stream name from NHD database.
County Name County in which stream segment is located.
Town Name Town in which stream segment is located.  Where a stream segment crosses town line(s), the given town is the one with the greatest segment representation.
HUC 12 12-digit USGS hydrologic unit code (watershed).
Drainage Drainage basin in which sampling site is located.
Site Sampling site.
Penobscot Divide   Site location: East or West of Penobscot River divide.
Year Year of sample collection.
Season Season of sample collection.  Sampling dates are consistent across all study sites within a season/year:

Spring 2003: May 7

Summer 2003: July 29

Fall 2003: October 28

Spring 2004: April 6

Summer 2004: July 27

Fall 2004: October 26.

Collection Sort Order Sort order to assist in graphing data: year-season.
pH, Closed Cell standard units Closed cell pH, determined with electrode.
pH, Air-Equilibrated standard units Air-equilibrated pH, determined with electrode.
ANC micro-equivalents per Liter (ueq/L) Acid-neutralizing capacity, determined by Gran titration.
Conductivity microSiemens per cm (uS) Specific conductance, determined with a Wheatstone bridge.
Color Platinum cobalt units Apparent color, determined by colorimetric comparison.
Dissolved Organic Carbon mg/L Dissolved organic carbon, determined by infrared carbon analyzer, persulfate oxidation.
Calcium micro-equivalents per Liter (ueq/L) Calcium, determined by Ion Chromatography.
Magnesium micro-equivalents per Liter (ueq/L) Magnesium, determined by Ion Chromatography.
Sodium micro-equivalents per Liter (ueq/L) Sodium, determined by Ion Chromatography.
Potassium micro-equivalents per Liter (ueq/L) Potassium, determined by Ion Chromatography.
Chloride micro-equivalents per Liter (ueq/L) Chloride, determined by ion chromatography.
Nitrate micro-equivalents per Liter (ueq/L) Nitrate, determined by ion chromatography Detection Limit: 0.1 ueq/L. Reporting Limit: 1.0 ueq/L.
Sulfate micro-equivalents per Liter (ueq/L) Sulfate, determined by ion chromatography.
Aluminum, Total micro-equivalents per Liter (ueq/L) Total dissolved aluminum, determined by Atomic Absorpbtion with graphic furnace.
Aluminum, Organic micro-equivalents per Liter (ueq/L) Organic aluminum, determined by Atomic Absorpbtion with graphic furnace.
Easting, Northing   UTM coordinates: NAD83, Zone 19.